58. Metallographie-Tagung 2024 - Materialographie
Vortrag
19.09.2024
Metallurgical Failure Investigation of Small Bore Piping on Diesel Hydrotreating Unit - wenn gleich drei Korrosionsschadenmechanismen am Werke sind
MG

Madeleine Giller

Siemens Energy Global GmbH & Co. KG

Giller, M. (V)¹; Neidel, A.²
¹Siemens Energy Global GmbH & Co. KG, Falkensee; ²Siemens Energy, Berlin
Vorschau
22 Min. Untertitel (CC)

Hydrocarbon leaks were repeatedly found in a refinery. Because of the recurring nature of this failure, the operator approached the authors´laboratory to get a second opinion on the metallurgical root cause of the failure. It was known from the customer that corrosive species, such as ammonium chloride salt precipitates, are present in the subject DHT unit. From the findings obtained in the investigation that is the subject of this contibution, the conclusion of the client´s metallurgical Root Cause Analysis, namely that the subject piping failed by transgranular chloride-induced stress corrosion cracking (Cl-SCC), could be verified and is indeed correct. The metallurgical root cause of the SBP failure is chloride-induced SCC. The morphology of the cracking is very distinct and is clearly consistent with transgranular Cl-SCC. A material change to the nickel-base material Alloy 625, already considered by the client, since this alloy is believed to be immune to chloride-induced SCC, would be a good, even though expensive solution. It should be emphasized that there are no metallic materials completely resistant to SCC, if the environment is harsh enough, except for some titanium alloys, i.e., if the source of the chloride ions cannot be eliminated, which is likely the case here, a regular inspection and replacement of these SBP systems might have to be considered. It should further be emphasized that a chloride concentration below 50 ppm is by no means any guarantee for the avoidance of SCC, since chlorides can concentrate in crevices, corrosion pits and such, i.e., the local, not the global concentration is what matters.

Abstract

Abstract

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