MSE 2024
Highlight Lecture
24.09.2024
High temperature oxidation of the CrFeNi medium entropy alloy
AM

Dr. Anna Manzoni

Bundesanstalt für Materialforschung und -prüfung (BAM)

Manzoni, A. (Speaker)¹; Hagen, S.²; Laplanche, G.³; Mohring, W.⁴; Schneider, M.⁵; Stephan-Scherb, C.⁶
¹Bundesanstalt für Materialforschung und -prüfung (BAM), Berlin; ²Friedrich-Alexander Universität Erlangen-Nürnberg; ³Institute of Materials, Bochum; ⁴50Hertz Transmission GmbH, Berlin; ⁵PSL University, Paris (France); ⁶Institute of Geoscience and Geography, Halle
Vorschau
17 Min. Untertitel (CC)

The oxidation behaviour of any alloy is a key issue which determines whether this material is suited for application. In this study, a single-phase equiatomic CrFeNi alloy was exposed to synthetic air at 1000 - 1100 °C for 24 - 1000 h and compared to 316L steel. The oxidation rate of CrFeNi was parabolic at the lower temperatures 1000 °C and 1050 °C, but at 1100 °C a first breakaway occurred after 4 h of exposure. In all cases, the oxide scales were found to partially spall off. As expected, Cr diffuses outwards to form a Cr2O3 layer at the gas/oxide interface. A thin layer of (Cr, Fe, Ni)3O4 is identified at the oxide/alloy interface. The CrFeNi alloy does not show any catastrophic oxidation behaviour at the investigated conditions unlike the 316L alloy, which contains more Mn and Fe.

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