FEMS EUROMAT 2023
Lecture
04.09.2023 (CEST)
Dual cation co-intercalation strategy for Mg batteries by employing dual-salt electrolytes: a case study of TiS2
AR

Ananyo Roy (M.Sc.)

Helmholtz-Institut Ulm für Elektrochemische Energiespeicherung

Roy, A. (Speaker)¹
¹Helmholtz Institute Ulm (HIU)
Vorschau
34 Min. Untertitel (CC)

Rechargeable Mg batteries suffer from poor mobility and kinetics of divalent Mg2+ in host cathode materials. In this work, we have employed the dual cation co-intercalation strategy to mitigate the sluggish intercalation kinetics of Mg ions. The working principle involved pairing sluggish Mg2+ with faster monovalent ions, Li+ and Na+. Layered TiS2 model cathode, together with a Mg metal anode were used for this study. Two dual cation systems were designed by using Mg[B(hfip)4]2-Li[B(hfip)4] (Mg-Li) and Mg[B(hfip)4]2-Na[B(hfip)4] (Mg-Na) dual-salt electrolytes. The dual cation systems delivered significantly higher initial discharge capacities of ~250 mAh g–1 in comparison to the initial discharge capacity of ~100 mAh g–1 (Fig. 1) delivered by the system employing the single-salt Mg [B(hfip)4]2 electrolyte.

Abstract

Abstract

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