FEMS EUROMAT 2023
Lecture
04.09.2023
Metal electrodeposition/stripping and 4D STEM analysis via operando liquid cell transmission electron microscopy
YP

Yevheniy Pivak (Ph.D.)

DENSsolutions

Pivak, Y. (Speaker)¹; Park, J.²; Weber, D.³; Jo, J.³; Sun, H.¹; Eichel, ‪.-A.⁴; Basak, S.⁵
¹DENSsolutions, Delft (Netherlands); ²Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Jülich; ³Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons and Peter Grünberg Institute, Jülich; ⁴Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Institute of Physical Chemistry, RWTH Aachen University, Jülich, Aachen; ⁵Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons and Peter Grünberg Institute, Jülich
Vorschau
23 Min. Untertitel (CC)

Aqueous metal batteries present new possibilities towards low cost and more sustainable energy storage. However, one of the main stumbling blocks to this battery technology is the growth of metal dendrites, which tend to cause battery premature failure and safety issues. Here, we employ liquid cell transmission electron microscopy (TEM) to directly visualized the electroplating and stripping of metals on micro electrodes at the nanoscale. Using operando liquid cell TEM, a new approach to liquid thickness manipulation and 4D STEM electron diffraction analysis, will reveal how the growth of Zn dendrites in Zn-ion batteries can be effectively controlled on electrochemical cycling.

Abstract

Abstract

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