Vanderbilt University
The reversible hydrogen-bromine (H2-Br2) redox flow battery has attracted considerable interest lately and is considered to be a suitable candidate for large scale electrical energy storage. In this talk, the fabrication and use of an electrospun nanofiber mat hydrogen electrode in a H2-Br2 redox flow battery is described, where the fibers are composed of Pt/C catalyst particles and Nafion binder. Due to enhanced surface hydrophobicity, there is little or no poisoning of the Pt catalyst by bromine species, resulting in high power generation at a low Pt loading and long cycle life, e.g., 550 mW/cm2 at 0.65 V for a loading of 0.048 mgPt/cm2 (11.5 kW/gPt), with no loss in power for more than 140 charge/discharge cycles.
Abstract
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