FEMS EUROMAT 2023
Poster
Fast charge storage in calcium batteries enabled by a novel porphyrin complex as cathode material
TS

Thomas Smok (M.Sc.)

Karlsruher Institut für Technologie (KIT)

Smok, T. (Speaker)¹; Abouzari-Lotf, E.²; Shakouri, S.¹; Pammer, F.²; Diemant, T.²; Roy, A.²; Xiu, Y.²; Klyatskaya, S.¹; Ruben, M.¹; Fichtner, M.²
¹Karlsruhe Institute of Technology (KIT), Eggenstein-Leopoldshafen; ²Helmholtz Institute Ulm (HIU)

In this work, a tetra-pyridyl porphyrin was utilized as cathode active material in calcium batteries, as porphyrins have already demonstrated that they can operate in versatile battery configurations including Li-, Na-, K-, Al- and Mg- batteries. Besides expansive characterization of the porphyrin active material itself, we have performed widescale electrochemical testing and found out that porphyrins showed interesting performance including good stability and high discharge capacities at elevated currents. To further boost these properties, we developed a copper containing framework, which was studied equivalently.

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