EWCPS 2025 - 20th European Winter Conference on Plasma Spectrochemistry
Poster
02.03.2025
Searching for a needle in a haystack: Preconcentration and matrix separation methods for Pb isotopic ratio measurements in seawater via MC ICP-MS
DW

Dominik Wippermann (M.Sc.)

Helmholtz-Zentrum Hereon GmbH

Wippermann, D. (Speaker)¹; Sprenger, J.¹; Ebeling, A.¹; Zimmermann, T.¹; Pröfrock, D.¹
¹Helmholtz-Zentrum hereon GmbH, Geesthacht

In this study we present two preconcentration methods for Pb isotopic ratio measurement via MC ICP-MS in seawater. One approach features freeze drying of the seawater with subsequent first matrix removal and preconcentration using an offline seaFASTTM system (Elemental Scientific) utilizing Nobias-PA-1 chelating resin. The second approach features a pressure filtration using Empore™ SPE Chelating Disks (CDS Analytical) for parallel preconcentration and first matrix removal. Further purification for both approaches was conducted by a fully automated separation of Pb using DGA Resin (TrisKem International) (Pb recovery >93%) as described by Retzmann et al. (2017). MC ICP-MS (Nu Plasma II, Nu Instruments Ltd.) measurements were conducted in static measurement mode with low mass resolution. Correction for instrumental isotopic fractionation (IIF) was based on standard-sample bracketing adapted from Horsky et al. (2016).

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