FEMS EUROMAT 2023
Lecture
05.09.2023
Resolving defect densities and lifetimes in perovskite solar cells using frequency domain methods
SR

Dr. Sandheep Ravishankar

Forschungszentrum Jülich GmbH

Ravishankar, S. (Speaker)¹; Rau, U.¹; Kirchartz, T.¹
¹Forschungszentrum Jülich GmbH
Vorschau
19 Min. Untertitel (CC)

Capacitance measurements as a function of voltage, frequency and temperature are a useful tool to gain deep insight into the electronic properties of semiconductor devices in general and of solar cells in particular. Techniques such as capacitance-voltage, Mott-Schottky analysis or thermal admittance spectroscopy measurements are frequently employed to perovskite solar cells in order to obtain relevant parameters of the perovskite absorber. However, state-of-the-art perovskite solar cells use thin electron and hole transport layers to improve the contact selectivity. These contacts are often quite resistive in nature, which implies that their resistance will significantly contribute to the total device impedance and thereby also affect the overall capacitance of the device, thereby partly obscuring the capacitance signal from the perovskite absorber. Based on this premise, we develop a simple multilayer model that considers the perovskite solar cell as a series connection of the geometric capacitance of each layer in parallel with their voltage-dependent resistances. Analysis of this model yields fundamental limits to the resolution of spatial doping profiles and minimum values of doping/trap densities, built-in voltages and activation energies. We observe that most of the experimental capacitance-voltage-frequency-temperature data, calculated doping/defect densities and activation energies reported in literature are within the derived cut-off values, indicating that the capacitance response of the perovskite solar cell is indeed strongly affected by the capacitance of its selective contacts. We further extend this model to the analysis of the lifetimes in the frequency domain, identifying that the transport layers strongly influence the measured lifetimes because the charge extraction through these layers is strongly coupled with the recombination in the perovskite layer.

Abstract

Abstract

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